Bulk Ion Chemical Reactions Model Reference

The Bulk Ion Chemical Reactions model allows you to model chemical reactions that involve electrochemical species which occur within a fluid domain.

The Bulk Ion Chemical Reactions model is an optional electrochemistry model which you use with the Electrochemical Reactions model and the Electrochemical Species model. You can use the Bulk Ion Chemical Reactions model to simulate chemical reactions that occur within the bulk volume of an electrolyte. This model is useful when modeling applications, such as electroless deposition and wet etching, in which the chemical reactions occur in a short timescale. Due to the short timescale of such reactions, the electrochemical species are assumed to reach equilibrium instantaneously.

Table 1. Bulk Ion Chemical Reactions Model Reference
Theory See Bulk Ion Chemical Reactions (Homogeneous).
Provided By [physics continuum] > Models > Reactive Flow
Example Node Path Continua > Physics 1 > Models > Bulk Ion Chemical Reactions
Requires
  • Material: Liquid
  • Reaction Regime: Reacting
  • Space: any
  • Optional Models: Electrochemistry
  • Electrochemistry: Electrochemical Species

After selecting Bulk Ion Chemical Reactions, select Electrochemical Reactions.

Properties Key properties are: [Enabled Trigger and Begin]. See Bulk Ion Chemical Reactions Properties.
Activates Field Functions Electrochemical Species Residence Time. See Field Functions.

Bulk Ion Chemical Reactions Properties

Source Enabled Trigger
Controls whether Simcenter STAR-CCM+ starts calculating the chemistry at the time-step, iteration, or physical time that you specify in the Begin property, or whether this model never contributes any sources.
Begin
Specifies the iteration, time-step, or physical time after which the reactions are activated. Before this iteration, time-step, or physical time, reactions are deactivated. This feature is useful when modeling significant flow as you can deactivate reactions until a flow solution is found.

Field Functions

Electrochemical Species Residence Time
Displays the residence time of electrochemical species within a specified volume. See Eqn. (4178).
Bulk Ion Production Rate of [electrochemical species]
Displays the total amount of the [electrochemical species] (kmol) that is produced per unit volume by the bulk ion chemical reactions model.