Ionic Species Flux

You can use the Electrochemical Species model within a liquid or gas to model the transport of ionic species, including, diffusion, convection, and migration/drift fluxes.

Ionic Species Flux

There are many chemical processes that rely on the migration of charged particles. In general, charged particles are referred to as ionic species which can represent positively or negatively charged ions. Modeling the flow and concentration of ionic species using Simcenter STAR-CCM+ provides a convenient and cost effective approach for comparing the efficiency of engineering processes. This ability is even more useful when raw materials for electrochemical applications are rare or expensive. You can simulate the behavior of ionic species realistically and prevent material waste by finding the most efficient setup using Simcenter STAR-CCM+. The option is provided to solve for electrochemical species concentrations using a coupled or segregated approach.

By modeling all relevant transport mechanisms for ionic species, you can predict the heterogeneity of ion concentrations within an electrolyte. The migration flux of an ionic species is proportional to the electric field in the electrolyte. You can only define the migration of ionic species when the Electrochemical Species model is selected along with one of the following models:

  • Electrodynamic Potential model

    Adding the Electrodynamic Potential model allows you to model applications such as:

    • paint delamination
    • pitting corrosion
    • crevice corrosion
    • galvanic corrosion
    • cathodic protection
    • electroplating
    • wet etching
    • flow batteries
    • metal-liquid interface reactions

    You additionally use the Electrochemical Reactions model when you want to model specific surface reactions in these applications.

  • Electrostatic Potential model

    Adding the Electrostatic Potential model allows you to model applications such as:

    • ionic wind simulations
    • electrostatic precipitators
    • plasma

If the Electrochemical Species model is used without either the Electrodynamic Potential or Electrostatic Potential model, Simcenter STAR-CCM+ can only calculate diffusion and convection flux, and not migration flux.

To model electrohydrodynamic forces that arise from local ionic charge densities, use the Coulomb Force model in addition to the Electrochemical Species model and Electrostatic Potential model. See Coulomb Force Formulation.