Setting the Electric Current Potential Characteristic

For some engineering applications, it is of interest to prescribe a characteristic relation of electric current to electric potential drop at a boundary or an interface. This characteristic relation can also be known as the potential-voltage characteristic or polarization curve.

Example applications where it is convenient to define the I-V characteristic at boundaries are:
  • cathodic protection, in which the complexity of the electro-chemical corrosion process is reduced to the polarization curve of a specific setup
  • diodes
  • photovoltaic elements
  • electron/ion emission into plasmas

You can specify an Electric Current Potential Characteristic condition at boundaries and contact interfaces when the Electrodynamic Potential Model is selected. For example:

  1. Select the [Region] > Boundaries > [Boundary] > Physics Conditions > Electric Potential Specification node and set the Method to Electric Current Potential Characteristic.
  2. Select the [Region] > Boundaries > [Boundary] > Physics Values > Current Voltage Characteristic node and in the Properties window, set Method to one of the following options:

Using the Butler-Volmer Method

When using the Butler-Volmer method, you specify the quantities that appear in the Butler-Volmer equation (see Eqn. (4296)) by setting the corresponding properties. See Current Voltage Characteristic Properties.

Using the Tabular Polarization Curve Method

The relationship between the specific electric current, jn , and the potential drop across the boundary or interface, ϕ1-ϕ0 is specified using tabular data. See Tabular Polarization Curve Properties.
  1. Select the [Region] > Boundaries > [Boundary] > Physics Values > Current Voltage Characteristic > Tabular Polarization Curve node and set the appropriate Tabular Polarization Curve Properties.
  2. Select the Tabular Polarization Curve > Table Sorting node and specify the Option.

    The Table Sorting Option is set to Electric Potential by default, which is appropriate for most applications. However, if you are setting up a plasma simulation with non-monotonic current voltage characteristics, you can select Specific Electric Current. See Table Sorting Properties.