Exothermic Solids

If temperature exceeds the ignition temperature of an exothermic (mold) material for the first time, a certain amount of energy is released over time.

In a simulation, the cells that represent the exothermic material each burn for the same amount of time, but at different times. This difference in timing makes it difficult to model an exothermic solid through a user-defined volumetric heat source.

To quantify this energy in Simcenter STAR-CCM+, use the Exothermic Solid model. This model is a simple combustion model that works like a heat source. When temperature in the solid exceeds ignition temperature, a user-specified heat source simulates combustion.

Two material properties, Autoignition Temperature and Power of Reaction, suffice to describe the entire effect of the exothermic solid material on the energy balance. For example, if a simulation involves two different exothermic solid materials, they would differ only in those material properties. There are no reaction constants or, for instance, no Arrhenius equation from which the energy release over time is computed; the Power of Reaction material property gives this quantity directly.

The main simplification is the Reaction Time field function. It returns the time that the temperature exceeds the Auto-Ignition Temperature.

The application for this model is exothermic mold materials. They are used to enhance feeding systems by extending the solidification time of the reservoirs of liquid metal which are intended to compensate for shrinkage on solidification. The exothermic reaction is initiated when molten metal meets the exothermic mold material.