Modeling Evaporation and Condensation

The particular phase-change type that is described in this section concerns evaporation and condensation.

What are Evaporation and Condensation?

Evaporation is a form of vaporization, the phase change from liquid to gas, which occurs when liquid molecules or atoms with high enough kinetic energy escape through the interface between the two phases. Condensation is the reverse process of vaporization and is the phase change from gas to liquid.



The Evaporation/Condensation model deals with evaporation (without boiling) and condensation taking place at the free surface interface between a liquid and gas phase within the context of the Volume Of Fluid method. Both phases are modeled as multi-component mixtures that can include non-interacting (inert) species [606], [605]. Evaporation and condensation are treated as hydrodynamically limited, meaning that:

  • The phases are considered to be in equilibrium at the interface, and
  • The driving force is the diffusion of species.

The grid must be sufficiently fine to model the transport of species away from and toward the interface accurately.

Raoult’s law is used to describe the phase equilibrium.

Evaporation/Condensation Properties

Connectivity Identifies the evaporating/condensing pairs in the liquid and the gas phases.