Using the Nernst-Einstein Method for Charged Species

The Nernst-Einstein method can be set to determine the mobility of charged species from the diffusivity, or the diffusivity from the mobility.

You can use this method to define the charged species mobility or diffusivity and determine the overall migration of ionic species in electrolytic solutions.

Computing diffusivity from mobility

(mobility is set to constant and molecular diffusivity is set to Nernst-Einstein)

Computing mobility from diffusivity

(mobility is set to Nernst-Einstein and molecular diffusivity is set to constant)

When mobility specified as ui, [m2kmol/Js]:

Diffusivity, Di, is determined from the mobility, ui, using Eqn. (4080).

(This scenario is default when using the Electrodynamic Potential model.)

Mobility, ui is determined from the diffusivity, Di, according to Eqn. (4080).

When mobility specified as Ki, [m2/Vs]:

Diffusivity, Di, is determined from the mobility, Ki, using Eqn. (4080) (in which ui is determined from Eqn. (4092)).

Mobility, Ki, is determined from the diffusivity, Di, according to Eqn. (4092) (in which ui is determined from Eqn. (4080)).

(This scenario is default when using the Electrostatic Potential model.)

Nernst-Einstein can be set as the Method for either Mobility or Molecular Diffusivity, but not for both. Therefore, to change the default settings for Mobility and Molecular Diffusivity, de-select Nernst-Einstein from one of the material properties methods before attempting to select it for the other. You can manually change the mobility dimensions from the default settings using the Electrochemical Species model property Charged Species Mobility Dimension.

You can also define the Method using a Field Function. See Using Field Functions.

Note If the physics continuum contains an energy model, the value of the local temperature is used for T in Eqn. (4080). If no energy model is active, a default value of 293.15K=20°C is used.