Using the Temperature Shift Factors

When temperature effects are present, the non-Newtonian liquid models use horizontal and vertical shift factors aT and bT to adjust viscosity with temperature.



When the simulation is independent of temperature, aT and bT=1. For polymers:

aTbT=ηTηT0

where η is the viscosity at temperature T and reference temperature T0.

The horizontal shift factor aT can be calculated by the Arrhenius model, the Nahme model, or the Williams-Landel-Ferry (WLF) model. The vertical shift factor bT can be calculated by the Rouse model.

Horizontal Temperature Shift Factor Methods

Arrhenius
Exposes the following terms from Eqn. (733):
  • E a : the activation energy.
  • T 0 : a reference temperature in K.

Use the Arrhenius model when the temperature is at least 100°C above the glass transition temperature of the polymer.

Nahme
Exposes the following terms from Eqn. (734):
  • E a : the activation energy.
  • T 0 : a reference temperature in K.

Use the Nahme model when the temperature is close to the reference temperature T 0 .

Williams-Landel-Ferry (WLF)
Exposes the following terms from Eqn. (735):
  • C 1 and C 2 : positive empirical constants that depend on the material and the reference temperature. See [24] for tables of values for C 1 , C 2
  • T 0 : a reference temperature in K.

Use the WLF model when the temperature is close to the glass transition temperature of the polymer.

Vertical Temperature Shift Factor Methods

Constant
This is the required method for non-isothermal simulations when the Viscoelastic model is active and its Square-root conformal property is On. The value of the constant must then be set to 1. Any constant value is allowed if the Square root conformal property is Off.
Rouse
Exposes the following term from Eqn. (736):
  • T 0 : a reference temperature in K.